Use of Non-GAAP Measures Page 3 -150.00% -50.00% 50.00% 150.00% 250.00% 350.00% PolyOne S&P 500 All time high of $34.47 December 9th, 2013 • 16 consecutive quarters of double digit EPS growth • 42% CAGR adjusted EPS expansion 2006-2012 • YTD stock price has increased 63% versus 27% growth in the S&P • More than six fold increase in market cap: $0.5b $3.3b Strategy and Execution Drive Results Page 4 The World’s Premier Provider of Specialized Polymer Materials, Services & Solutions Four Pillar Strategy Page 5 PP&S 15% Specialty 60% Distribution 25% 0.12 0.27 0.21 0.13 0.68 0.82 1.00 2.50 $0.00 $0.25 $0.50 $0.75 $1.00 $1.25 $1.50 $1.75 $2.00 $2.25 $2.50 2006 2007 2008 2009 2010* 2011* 2012* 2015 Target A dj us te d Ea rn in gs P er S ha re Appliance 6% Building & Construction 13% Wire & Cable 9% Electrical & Electronics 4% Consumer 9% Packaging 18% Industrial 10% Misc. 5% HealthCare 9% Transportation 16% Textiles 1% United States 70% Europe 14% Canada 8% Asia 5% Latin America 3% 2012 Revenues: $4.0 Billion* End Markets* 2012 Revenues: $4.0 Billion* EPS Page 6 * Pro Forma includes FY2012 results for Spartech (11/03/12 YE) and Glasforms & excludes discontinued operations PolyOne At A Glance * Restated to exclude discontinued operations Old PolyOne Transformation *Operating Income excludes corporate charges and special items 2% 34% 43% 63% 65- 75% 0% 20% 40% 60% 80% 100% 2005 2008 2010 YTD 2013 2015 % o f O pe ra ti ng In co m e* JV's PP&S Distribution Specialty Specialty OI $5M $46M $87M $153M Target Mix Shift Highlights Specialty Transformation 2015 Target Page 7 2006 YTD 2013 2015 Where we were Where we are Organic Consolidated Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 12.8% 12.8% 12 – 16% Global Specialty Engineered Materials 1.1% 10.8% 8.9% 12 – 16% Designed Structures & Solutions — — 5.0% 8 – 10% Performance Products & Solutions 5.5% 8.0% 8.2% 9 – 12% Distribution 2.6% 6.1% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 63% 65 – 75% 3) ROIC* (after-tax) 5.0% 9.4% 15% 4) Adjusted EPS Growth N/A 28% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period Page 8 *Percentage of Specialty Platform revenue from products introduced in last five years 19.5% 44.0% 2006 Q3 2013 $20.3 $46.6 2006 TTM Q3'13 14.3% 31.0% 2006 Q3 2013 Research & Development Spending Specialty Platform Vitality Index Progression* Innovation Drives Earnings Growth ($ millions) Specialty Platform Gross Margin % Page 9 We are Experts in Polymer Science and Formulation  Polymer Science  Formulation  Chemistry  Processing Inputs  Base Resins  Additives  Modifiers  Colorants Specialized Polymer Materials, Services, and Solutions Expertise Satisfied Consumers PolyOne Customer Innovative Products & Services  Marketplace Demands  Performance Requirements  Value Drivers Page 10 Positioned for Strong Growth 2015 Target Rev: $5B Adj. Average Debt Q3 2012 Q4 2012 Q1 2013 Q2 2013 Q3 2013 Average PolyOne Debt $ 705.2 $ 706.9 $ 1,055.5 $ 1,031.2 $ 987.7 $ 897.3 Average Equity Q3 2012 Q4 2012 Q1 2013 Q2 2013 Q3 2013 Average PolyOne shareholders’ equity $ 629.3 $ 629.1 $ 871.8 $ 993.9 $ 996.6 $ 824.1 Reconciliation to Condensed Consolidated Balance Sheets YTD 2013 Short-term debt and current portion of long-term debt $ 9.9 Long-term debt 977.8 Less cash and cash equivalents (322.8) Net debt $ 664.9 Adjusted EBITDA Q4 2012 Q1 2013 Q2 2013 Q3 2013 Total PolyOne Income before income taxes $ (1.1) $ 15.7 $ 62.9 $ 38.8 $ 116.3 PolyOne Interest expense, net 13.7 15.6 16.6 16.0 61.9 PolyOne Depreciation and amortization 15.5 19.0 25.8 30.3 90.6 PolyOne Special items in EBITDA 26.5 27.7 (5.2) 11.2 60.2 PolyOne Adjusted EBITDA 54.6 78.0 100.1 96.3 329.0 Pro forma Spartech EBITDA 14.7 11.2 - - 25.9 Pro forma EBITDA $ 69.3 $ 89.2 $ 100.1 $ 96.3 $ 354.9 PolyOne Investor Presentation��Bank of America Merrill Lynch�2013 US Basic Materials Conference�2013年12月11日� Forward – Looking Statements Use of Non-GAAP Measures Strategy and Execution Drive Results Four Pillar Strategy PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Proof of Performance & 2015 Goals Innovation Drives Earnings Growth We are Experts in Polymer Science and Formulation Positioned for Strong Growth Q3 2013 Financial Highlights Debt Maturities & Liquidity Summary – 9/30/13 Use of Cash Why Invest In PolyOne?

The portfolio consists of formulations which have specifically been developed for a broad range of applications. A small amount of specially formulated Hydrocerol concentrates will reduce these blemishes significantly.

Did you know that with the right formulation, you can achieve properties that are as good or better than that of PA 6,6 using materials such as PA 6, PK, PBT/PET, PP, polymer blends and even post-industrial recycled blends?

Syncure™ XLPE Cross-linkable Polyethylene Formulations FOR LOW VOLTAGE CABLES PRODUCT SELECTION GUIDE Syncure™ XLPE MOISTURE CROSS-LINKABLE POLYETHYLENE INSULATION FOR LOW VOLTAGE CABLE SYSTEMS SYSTEM S100FH S100FH-XUV S100FH-UV S100FV S100FV-UV S112NA S120NA S200FH S200FV Applications Building Wire, Tray Cable Building Wire, Tray Cable Photo-Voltaic (PV) Wire Building Wire, Tray Cable Building Wire, Tray Cable Building Wire, Teck-90 Pipe and Tube Building Wire, Tray Cable, Service Entrance Building Wire, Tray Cable, Service Entrance Specification UL 44 UL 44 UL 44, UL 4703 UL 44 UL 44 CSA 22.2 Suitable for NSF 61 UL 44 UL 44 Wire Type XHHW-2, RHW-2, USE-2, SIS XHHW-2, RHW-2, USE-2, SIS XHHW-2, RHW-2, USE-2, SIS, PV XHHW-2, RHW-2, SIS XHHW-2, RHW-2, USE-2, SIS, PV RW-90, Teck-90 – RHW-2, RHW, RHH, XHHW-2, XHH, XHHW, SIS RHW, RHH, RHW-2 Components % 83% S1054A 17% V0022G RoHS 83% S1054A 17% V0022G-UV RoHS 70% S1054A 30% V0022G-UV RoHS 50% S1054A 50% V0044G RoHS 50% S1054A 50% V0044G-UV RoHS 95% S1054A 5% S1000B 95% S1016A 5% S1037B 78% S1054A 22% SC5400-0002 RoHS MB ALT FR 50% S1054A 50% SC5400-0003 RoHS MB ALT FR Features Horizontal Flame Horizontal Flame, UV Resistant, Colors Possible Horizontal Flame, FV-1 Flame, UV Resistant, Colors Possible VW-1 VW-1, UV Resistant, Colors Possible Non-FR Rigid Pipe Applications Horizontal Flame, DBDPE-free VW-1, DBDPE-free GENERAL PROPERTIES Specific Gravity 1.01 1.02 1.10 1.31 1.31 0.92 0.95 1.01 1.31 Hardness Shore D, 10 Seconds 47 47 47 48 48 47 59 47 48 Gel 68 68 70 70 70 72 72 68 70 TENSILE PROPERTIES Tensile Strength (psi) 2800 2500 2650 3200 2650 2800 4500 2800 3200 Elongation % 400 400 540 470 540 400 80 400 470 Tensile Retention % 100 100 97 110 110 95 75 95 100 Elongation Retention % 90 90 94 100 100 90 75 90 93 ELECTRICAL Dielectric Strength (V/mil) 1000 1400 1400 1200 1200 1000 – 1000 1200 Dielectric Constant 2.31 2.45 2.61 2.61 2.61 2.24 2.1 2.31 2.61 Dissipation Factor % 0.0012 0.0080 0.008 0.0043 0.0043 0.0008 0.002 0.0012 0.0043 THERMAL Temperature Rating °C 90 90 90 90 90 90 125 90 90 Heat Deformation % 10 5 5 5 5 10 10 10 5 The Syncure™ XLPE portfolio is a two-step, silane- grafted, moisture cross-linkable polyethylene system.

ECCOH™ LSFOH 6153/6154 UV Formulations Improved processing speeds & greater gel resistance for optical fiber cables ECCOH™ LSFOH 6153 UV and 6154 UV grades are low smoke, fume, non-halogen material solutions for optical fiber cables with increased processing speeds and greater resistance to chemicals such as gel water blocking compounds, used to protect optical fibers.

Formulated with non-wick coating POPULAR RIPCORD PRODUCTS MOVING HIGH PERFORMANCE FIBERS FORWARD LOCATIONS Headquarters, R&D, Manufacturing FIBER-LINE® LLC 3050 Campus Drive Hatfield, PA 19440 +1 215.997.9181 fiber@fiber-line.com Manufacturing Operations FIBER-LINE® LLC 280 Performance Drive SE Hickory, NC 28602 +1 828.326.8700 fiber@fiber-line.com EMEA & Asia Pacific Operations FIBER-LINE® INTERNATIONAL B.V.

Using the new Complēt long glass fiber nylon formulation, the redesigned yoke underwent testing at Bettcher to simulate 500,000 run cycles.

With its unique formulation, ColorMatrix AAnchor offers improved recyclability, reduced regulatory risk, and enhanced bottle quality, making it an ideal solution for brands looking to incorporate higher levels of recycled material into their packaging.

AVIENT SOLUTIONS: • Bio-derived polymers • Soft touch materials • Conductive formulations *Source: Grandview Research, June 2019 PLAYFUL DELIGHT Embrace the playfulness of a puppy with bold, exciting colors and digital prints, mixed and mashed to create a playful look.

Customized color solutions are available on request • Production under ISO 13485 / GMP quality system with change control management • Fingerprinting of raw materials and routine batch testing • Extractability evaluated in hexane, isopropanol, and water according to ISO 10993 part 18 REGULATORY SUPPORT • Raw materials are pre-tested to biologically- evaluated raw materials using ISO 10993-1 and USP chapters , Class VI • DMF/MAF documentation filed with the FDA for all standard colors APPLICATIONS MEVOPUR LQ formulations can be applied in demanding applications including: • Medical devices such as catheter tubing & connectors, syringe tips, and needleless connectors • Skin contact devices such as wearables or soft-touch surfaces of medical devices PRODUCT BULLETIN MEVOPUR™-LQ YELLOW (PMS1205C) Product Code FZ1M415005 MEVOPUR™-LQ TRANS YELLOW Product Code FZ1M415006 MEVOPUR™-LQ BLUE (PMS292C) Product Code FZ5M415008 MEVOPUR™-LQ TRANS BLUE Product Code FZ5M415009 MEVOPUR™-LQ RED (PMS198C) Product Code FZ3M415008 MEVOPUR™-LQ TRANS RED Product Code FZ3M415009 MEVOPUR™-LQ GREEN (PMS346C) Product Code FZ6M415008 MEVOPUR™-LQ TRANS GREEN Product Code FZ6M415009 MEVOPUR™-LQ VIOLET (PMS2655C) Product Code FZ4M415003 MEVOPUR™-LQ TRANS VIOLET Product Code FZ4M415004 CUSTOM-MADE Individual options Customized colors are also available to meet your needs, please contact us.